Product ID:347, HAI-347SS
MSDS Date:08/21/1989
FSC:9540
NIIN:00N032126
MSDS Number: BNSLC

HARRISON ALLOYS INC

308 MIDDLESEX ST
HARRISON, NJ 07029
US

Emergency Phone: 201-483-4800

Info Phone: 201-483-4800

Cage: 49076

HARRISON ALLOYS INC

HARRISON, NJ 07029 US

Telephone: 201-483-4800

Cage: 49076

SILICON

CAS: 7440-21-3

RTECS: VW0400000

Fraction By Weight: 1 - 4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

COLUMBIUM

CAS: 7440-03-1

PUBLICATION F2.2.

RTECS: 9999999ZZ

CHROMIUM (SARA III)

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 18%

OSHA PEL 1 MG/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

IRON (III) OXIDE; (IRON)

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: 67%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG/M3(FE),B2; 9293

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: 2%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

NICKEL (SARA III)

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 11%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:UNDER NORM HNDLG & USE,EXPOS TO SOLID,
MASSIVE FORMS OF ALLOY PRESENTS FEW HLTH HAZ. THEY MAY INCL SKIN
IRRIT/ OTHER ALLERGIC RXNS IN SENSITIVE INDIV. ACUTE: NAUS,
TIGHTNESS OF CHEST, FEVER, IRRIT OF EYES, NOSE, THROAT & SKIN;LOSS
OF CONSCIOUSNESS DUE TO WELDING GASES/LACK OF O2. CHRONIC: ADVERSE
EFTS (EFTS OF OVEREXP
Explanation of Carcinogenicity:NICKEL: NTP:ANTICIPATED TO BE A
CARCINOGEN; GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ: MAY INCL SKIN SENSIT, NEURO DMG &
RESP DISEASES (BRONCH ASTHMA, LUNG FIBROSIS/PNEUMOCONIOSIS). ACCORD
TO OSHA 29CFR 1910.1200 NICKEL & CHROMIUM ARE CONSIDERED POSS
CARCIN. RECENT EPIDEMIOLOG ICAL STUDIES OF WORKERS MELTING &
WORKING ALLOYS CONTAINING NICKEL-CHROMIUM HAVE FOUND NO INCR RISK
OF CANCER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION: REMOVE FROM EXPOSURE AND OBTAIN PROMPT MEDICAL
ATTENTION. ADMINISTER OXYGEN IF VICTIM IS UNCONSCIOUS. IF NOT
BREATHING, RESUSITATE IMMEDIATELY. INGESTION: CALL MD IMMEDIATELY .
SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER . EYE: FLUSH WITH WATER
FOR AT LEAST 15 MINUTES .

Flash Point:NONFLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATERIAL IS NONFLAMMABLE; HOWEVER,
WELDING ARCS AND SPARKS CAN IGNITE FLAMMABLE LIQUIDS AND VAPORS AND
COMBUSTIBLE SOLIDS.

Spill Release Procedures:UNDER NORM HNDLG & USES MATL IS NOT VOLAT/
DUSTY & DOES NOT PRESENT SPILLAGE & LEAKAGE PROBLEMS. NO PROT REQD,
EXCEPT AVOID PRLNGD/RPTD DIRECT SKIN CONT IF SENSITIVE TO METALS.
USE GLOVES. IF HOWEVER, MATLS ARE RELS/SPILLED FROM CUTTING,
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MATERIAL IN SOLID FORM DOES NOT
REQUIRE SPECIAL PRECAUTIONS IN HANDLING AND STORING.
Other Precautions:USE INDUSTRIAL HYGIENE AIR MONITORING TO ENSURE THAT
USE OF MATERIAL DOES NOT CREATE EXPOSURES WHICH EXCEED LEVELS
SPECIFIED IN INGREDIENTS.

Respiratory Protection:IF SOLID METAL ALLOYS ARE CONVERTED IN MFG(INCL
GRINDING, HIGH TEMP CUTTING & WELDING) PROCESSES TO DUSTS,FUMES,
GASES/ MISTS,& VENT IS NOT ADEQ TO MAINTAIN EXPOS BELOW LIMITS
SPECIFIED IN INGREDS, TH EN RESP PROT SHOULD BE USED. USE (SUPDAT
Ventilation:IF SOLID METAL ALLOYS ARE CONVERTED TO DUSTS,FUMES/MISTS,
MAINTAIN WORKING ENVIRON BELOW EXPOS LIMITS SPECIFIED (SUPDAT)
Protective Gloves:LEATHER OR RUBBER GLOVES RECOMMENDED.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WHEN CUTTING,GRINDING/WELDING, WEAR FACE
PROTECTION & FLAME RETARDANT CLTHG. SELECT WELDING LENSE SHADE FROM
AWS (ING 7)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PRODS: OXIDES OF METALS, CHROMATES, FLUORIDES & COMPLEX
METALLICS. GASES MAY INCL CO,OZONE & NOX. SPILL PROC:
GRINDING/WELDING OPER,VACUUM RESIDUE INTO SUITABLE CNTNRS & DISP OF
I/A/W EPA/L OC REGS. RESP PROT:ONLY NIOSH/MSHA APPRVD RESP I/A/W
OSHA 29CFR1910.134. VENT:IN INGREDS SEC BY USE OF ADEQ EXHST VENT.

HCC:N1
Boiling Pt:B.P. Text:4982F,2750C
Melt/Freeze Pt:M.P/F.P Text:2642F,1450C
Spec Gravity:7.9
Solubility in Water:NONE
Appearance and Odor:GREY METALLIC, ODORLESS, ALLOY PRODS ARE SOLID
METALS SHAPED AS WIRE, ROD/STRIP
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
AVOID ACIDS. CONTACT WITH MINERAL ACIDS WILL RELEASE HYDROGEN-A VERY
READILY FLAMMABLE GAS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES & GASES FROM WELDING & HIGH TEMP
CUTTING CONTAIN CONSTITUENTS DIFFERENT FROM INGREDS LISTED & MAY
INCL (SUPDAT)

Waste Disposal Methods:VACUUM RESIDUE INTO SUITABLE CONTAINERS AND
DISPOSE OF IN ACCORDANCE WITH EPA OR LOCAL REGULATIONS. DISPOSE OF
IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .

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